| Kolo | Datum/Vreme | Utakmica | Rezultat |
|---|---|---|---|
| 1 | 16.08.2024 19:00 | Celta Vigo - Deportivo Alavés | 2:1 |
| 2 | 25.08.2024 19:15 | Deportivo Alavés - Real Betis | 0:0 |
| 3 | 28.08.2024 21:30 | Real Sociedad - Deportivo Alavés | 1:2 |
| 4 | 01.09.2024 17:00 | Deportivo Alavés - Las Palmas | 2:0 |
| 5 | 14.09.2024 16:15 | Espanyol - Deportivo Alavés | 3:2 |
| 6 | 20.09.2024 21:00 | Deportivo Alavés - Sevilla | 2:1 |
| 7 | 24.09.2024 21:00 | Real Madrid - Deportivo Alavés | 3:2 |
| 8 | 28.09.2024 14:00 | Getafe - Deportivo Alavés | 2:0 |
| 9 | 06.10.2024 16:15 | Deportivo Alavés - Barcelona | 0:3 |
| 10 | 18.10.2024 21:00 | Deportivo Alavés - Real Valladolid | 2:3 |
| 11 | 26.10.2024 16:15 | Rayo Vallecano - Deportivo Alavés | 1:0 |
| 12 | 01.11.2024 21:00 | Deportivo Alavés - Mallorca | 1:0 |
| 13 | 09.11.2024 16:15 | Villarreal - Deportivo Alavés | 3:0 |
| 14 | 23.11.2024 16:15 | Atlético Madrid - Deportivo Alavés | 2:1 |
| 15 | 30.11.2024 16:15 | Deportivo Alavés - Leganés | 1:1 |
| 16 | 08.12.2024 18:30 | Osasuna - Deportivo Alavés | 2:2 |
| 17 | 15.12.2024 16:15 | Deportivo Alavés - Athletic Club | 1:1 |
| 18 | 22.12.2024 14:00 | Valencia - Deportivo Alavés | 2:2 |
| 19 | 11.01.2025 19:00 | Deportivo Alavés - Girona FC | 0:1 |
| 20 | 19.01.2025 19:00 | Real Betis - Deportivo Alavés | 1:3 |
| 21 | 27.01.2025 21:00 | Deportivo Alavés - Celta Vigo | 1:1 |
| 22 | 02.02.2025 14:00 | Barcelona - Deportivo Alavés | 1:0 |
| 23 | 09.02.2025 19:00 | Deportivo Alavés - Getafe | 0:1 |
| 24 | 15.02.2025 14:00 | Leganés - Deportivo Alavés | 3:3 |
| 25 | 22.02.2025 14:00 | Deportivo Alavés - Espanyol | 0:1 |
| 26 | 02.03.2025 18:30 | Mallorca - Deportivo Alavés | 1:1 |
| 27 | 08.03.2025 19:00 | Deportivo Alavés - Villarreal | 1:0 |
| 28 | 14.03.2025 21:00 | Las Palmas - Deportivo Alavés | 2:2 |
| 29 | 29.03.2025 18:30 | Deportivo Alavés - Rayo Vallecano | 0:2 |
| 30 | 05.04.2025 14:00 | Girona FC - Deportivo Alavés | 0:1 |
| 31 | 13.04.2025 16:15 | Deportivo Alavés - Real Madrid | 0:1 |
| 32 | 20.04.2025 18:30 | Sevilla - Deportivo Alavés | 1:1 |
| 33 | 23.04.2025 21:30 | Deportivo Alavés - Real Sociedad | 1:0 |
| 34 | 03.05.2025 14:00 | Deportivo Alavés - Atlético Madrid | 0:0 |
| 35 | 11.05.2025 18:30 | Athletic Club - Deportivo Alavés | 1:0 |
| 36 | 14.05.2025 19:00 | Deportivo Alavés - Valencia | 1:0 |
| 37 | 18.05.2025 19:00 | Real Valladolid - Deportivo Alavés | 0:1 |
| 38 | 24.05.2025 21:00 | Deportivo Alavés - Osasuna | 1:1 |
| Poz | Tim | Utak | Pob | Ner | Por | DG | PG | GR | Forma | Bod | |
| 1 | Barcelona | 38 | 28 | 4 | 6 | 102 | 39 | +63 | 1 1 1 2 1 | 88 | |
| 2 | Real Madrid | 38 | 26 | 6 | 6 | 78 | 38 | +40 | 1 2 1 1 1 | 84 | |
| 3 | Atlético Madrid | 38 | 22 | 10 | 6 | 68 | 30 | +38 | X 1 2 1 1 | 76 | |
| 4 | Athletic Club | 38 | 19 | 13 | 6 | 54 | 29 | +25 | X 1 1 1 2 | 70 | |
| 5 | Villarreal | 38 | 20 | 10 | 8 | 71 | 51 | +20 | 1 1 1 1 1 | 70 | |
| 6 | Real Betis | 38 | 16 | 12 | 10 | 57 | 50 | +7 | 1 X X 2 X | 60 | |
| 7 | Celta Vigo | 38 | 16 | 7 | 15 | 59 | 57 | +2 | 2 1 1 2 1 | 55 | |
| 8 | Osasuna | 38 | 12 | 16 | 10 | 48 | 52 | -4 | 2 X 1 1 X | 52 | |
| 9 | Rayo Vallecano | 38 | 13 | 13 | 12 | 41 | 45 | -4 | 1 1 X 1 X | 52 | |
| 10 | Mallorca | 38 | 13 | 9 | 16 | 35 | 44 | -9 | 2 1 2 2 X | 48 | |
| 11 | Valencia | 38 | 11 | 13 | 14 | 44 | 54 | -10 | 1 1 2 2 X | 46 | |
| 12 | Real Sociedad | 38 | 13 | 7 | 18 | 35 | 46 | -11 | X 2 2 1 2 | 46 | |
| 13 | Getafe | 38 | 11 | 9 | 18 | 34 | 39 | -5 | 2 2 2 1 2 | 42 | |
| 14 | Deportivo Alavés | 38 | 10 | 12 | 16 | 38 | 48 | -10 | X 2 1 1 X | 42 | |
| 15 | Espanyol | 38 | 11 | 9 | 18 | 40 | 51 | -11 | 2 2 2 2 1 | 42 | |
| 16 | Sevilla | 38 | 10 | 11 | 17 | 42 | 55 | -13 | X 2 1 2 2 | 41 | |
| 17 | Girona FC | 38 | 11 | 8 | 19 | 44 | 60 | -16 | 1 2 1 2 2 | 41 | |
| 18 | Leganés | 38 | 9 | 13 | 16 | 39 | 56 | -17 | X 1 2 1 1 | 40 | |
| 19 | Las Palmas | 38 | 8 | 8 | 22 | 40 | 61 | -21 | 2 2 2 2 2 | 32 | |
| 20 | Real Valladolid | 38 | 4 | 4 | 30 | 26 | 90 | -64 | 2 2 2 2 2 | 16 | |
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